

           
Furrow Pump, Inc.
P.O.
Box 1849
8525 SW
St. Helens Dr.
Wilsonville,
OR 97070
Phone:
(800) 937-3666
FAX:
(800) 377-9960
www.furrowpump.com
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EXPLANATION
RELATIVE pH SOLUTION STRENGTH & NORMALITY CONVERSIONS
I've found the information in TABLE 2 hard to come by. I don't know about you, but the
importance of a solution's Normality was not at the front of my mind. Not to mention
what it was, or how to calculate it. But the information is really quite
useful. Normality is the way a chemist says six of this is equal to a half-dozen of
that: The gram equivalent weight of an acid, base or salt is that fraction of its
molecular weight which contains (for acids) or is equivalent to (for bases and salts) one
gram atomic weight of displaceable hydrogen. If you divide a compound's molecular
weight by the number of ions that readily dissociate in water, you get its equivalent
weight. |
Equivalent
Weight = |
Molecular Weight |
Valence |
In
the case of sulfuric acid, two hydrogens separate easily from the sulfate. For
sodium hydroxide, the equivalent of one hydrogen separates from the sodium. Their
equivalent weights, then, are shown below:
For H2SO4
: |
98 |
= |
49 |
For NaOH :
|
40 |
= |
40 |
| 2 |
1 |
A normal concentration, or One Normal Solution (1 N) contains one gram equivalent weight
of acid, base or salt for every liter of solution. Using the "this equals
that" analogy, 40 gallons of a 1 N sulfuric acid solution would neutralize 40 gallons
of a 1 N sodium hydroxide solution. |
For most of us involved with water treatment, however, normal solution values are not
readily available. Most of the regularly used acids and bases, along with our Jar
Testing chemicals, are listed in TABLE 2. To compare these
chemicals to one another, I assigned baking soda (0.25N) a value of one. This is
convenient for use with our Jar Testing section, since pump sizing and chemical volumes
can be easily estimated. In addition, comparisons of relative strength can be
made. For example, a one pound per gallon solution of soda ash (approximately 10 %)
has a relative strength of 4, while a 25 % solution of sodium hydroxide has a relative
strength of 40. You would therefore need 10 times less of the sodium hydroxide
solution than the soda ash solution, to do the same job.. |
One last note of explanation: In the real world, we generally are given percentage
concentrations for the chemicals we deal with. When I looked around for a way to
convert percentages into Normality, I couldn't find it. If you can figure out the
Specific Gravity and equivalent weight for a chemical, the following formula will do that
conversion: |
Normality
= |
10 x Specific Gravity x % Concentration |
Equivalent Weight |
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Note: |
Strong
Acids |
HCL |
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(100 %
Ionized) |
HNO3 |
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H2SO4 |
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Weak
Acids |
C2H4O2 |
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C6H8O7 |
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H3PO4 |
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